This paper presents the results of a preliminary study to assess the potential of the visible, NIR and SWIR energy of the EMR in differentiating iron ores of different grades in a rapid manner using hyperspectral radiometry. Using different iron ore samples from Noamundi and Joda mines, Jharkhand and Orissa, states of India, certain spectro-radiometric measurements and geochemical analysis were carried out and the results have been presented.